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a ) The CGC possess the symmetry property hl 1 , l 2 ; m 1 , m 2 | l , mi = (

a) The CGC possess the symmetry property
hl1, l2; m1, m2|l, mi =(1)ll1l2
hl2, l1; m2, m1|l, mi.(1)
Use this property to show that for two electrons in equivalent orbitals the total orbital
angular momentum quantum number l must have even values for singlet (spin) states and
odd values for triplet states.
b) Prove the recurrence relation
hl1, l2; m11, m2+1|l, li =
s
l2(l2+1) m2(m2+1)
l1(l1+1) m1(m11)hl1, l2; m1, m2|l, li (2)
c) Verify this recurrence relation explicitly for the coefficient hl1, l2; m1, m2|l, li = h1,
1
2
; 1,
1
2
|
1
2
,
1
2
i
using the table on the next page.

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