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A twist - boat conformation may be obtained by slightly twisting carbon atoms 2 and 5 while keeping atoms 1 and 4 above or beneath
A twistboat conformation may be obtained by slightly twisting carbon atoms and while
keeping atoms and above or beneath the other atoms. Twisting too far will lead to the chair
conformation.
twistboat contormation
Note how carbons and are no longer coplanar.
a Compare the number of eclipsing interactions in the twistboat and boat conformations.
Which one has more?
b Rank the chair, boat, and twistboat conformations in order of increasing stability.
c Which one of these will have the most negative energy value?
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