Question
Acetic acid is to be recovered from a waste solvent mixture containing 50 wt% acetic acid in water. It is proposed that this will be
Acetic acid is to be recovered from a waste solvent mixture containing 50 wt% acetic acid in water. It is proposed that this will be done using a counter current solvent extraction column, where pure isopropyl ether is to be used as an extract solvent. The feed mixture of acetic acid and water will enter the column at a rate of 150 kg hr-1 . The column will operate at 1 atmosphere pressure and 25 C. Initially assuming a feed to solvent ratio of 1.
Please perform hand calculations to determine the following:
The number of ideal stages required to produce a raffinate stream containing not more than 10 wt % acetic acid. Stating clearly what the actual composition of the resulting raffinate stream will be and its mass flow in kg hr-1 .
The composition and mass flow rate of the extract stream leaving the column
Equilibrium data of ternary mixture:
Water Phase (Weight %) | Solvent Phase (Weight %) | ||||
Water | Acetic acid | isopropyl ether | Water | Acetic acid | Isopropyl ether |
93.52 | 5.96 | 0.52 | 0.32 | 8.75 | 90.93 |
82.23 | 17.04 | 0.73 | 1.1 | 25.14 | 73.76 |
72.06 | 26.92 | 1.02 | 2.27 | 38.52 | 59.21 |
67.95 | 30.88 | 1.17 | 3.11 | 42.97 | 53.92 |
62.67 | 35.73 | 1.6 | 4.26 | 48.21 | 47.53 |
57 | 40.9 | 2.1 | 6.05 | 53.95 | 40 |
50.2 | 46.05 | 3.75 | 8.9 | 57.4 | 33.7 |
41.7 | 51.78 | 6.52 | 13.4 | 60.34 | 26.26 |
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