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An analyst needs to evaluate the potential effect of an interferent, I, on the quantitative analysis for an analyte, A . She begins by measuring

An analyst needs to evaluate the potential effect of an interferent, I, on the quantitative analysis for an analyte, A. She begins by measuring the signal for a sample in which the interferent is absent and [A]=15.0 ppm and obtains a mean signal of 24.3. When she analyzes a sample in which the analyte is absent and [I]=75.0 ppm, she obtains a mean signal of 12.7. a.) What is the sensitivity for the analyte (kA)? b.) What is the sensitivity for the interferent (kI)? c.) What is the selectivity coefficient for this method (KA,I)? d.) Calculate the signal of a sample if it is composed of [A]=10.0 ppm and [I]=20.0 ppm. e.) If [A] is 10.0 ppm, what is the maximum [I] if the error in the signal must be less than 1%?

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