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At 5 C the reaction of ketene to diketene 2 ( C H 2 = C O ) ( C H 2 = C O

At 5C the reaction of ketene to diketene
2(CH2=CO)(CH2=CO)2
occurs rather slowly in the liquid phase, with second order kinetics
-rket =kCket2. We wish to design a flow process to treat a ketene feed (v0=0.8m3hr)
to 98% conversion in 2 horizontal tanks in series, each mechanically agitated and
having 3 well mixed compartments. In a batch reactor this conversion would re-
quire a 12 hour reaction time.
(a) In theory, what volume would be required for 1 PFR?
(b) What tank volume would be needed to do this is 1 CSTR?
(c) What about 2 CSTRs and what is the total of the two?
(d) Now for the design objective of 6 total well-mixed flow compartments, and
what is the total of the 6? Hint: do not try to solve this one analytically. Instead
develop an expression that relates xi, the conversion leaving compartment i,
to xi-1. Then try to find a volume that will give the correct x6 and x0.
(e) What is the size of each of the two tanks? Assume the internals (i.e. the ag-
itators, baffles, cooling coils, etc.) occupy 10% of the tank volume. State any
assumptions, such as constant liquid density. Draw or create a picture of your
reactors with you standing next to it for scale.
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