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( C H 3 ) 3 C O O C ( C H 3 ) 3 C 2 H 6 + 2 C H 3

(CH3)3COOC(CH3)3C2H6+2CH3COCH3
AB+2C
Chapter 6 Questions and Problems
239
is carried out isothermally at 400K in a flow reactor with no pressure drop. The specific reaction rate at 50C is 10-4min-1(from pericosity data) and the activation energy is 85kJmol. Pure di-tert-butyl peroxide enters the reactor at 10atm and 127C and a molar flow rate of 2.5molmin, i.e.,FA=2.5molmin.
(a) Use the algorithm for molar flow rates to formulate and solve the problem. Plot FA,FB,FC, and then x as a function of plug-flow reactor volume and space time to achieve 90% conversion.
(b) Calculate the plug-flow volume and space time for a CSTR for 90% conversion.
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