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Carbon tetrachloride CCl4 at 20 o C has a=12.4x10^-4, b=103x10^-6 atm^-1 p=1.5942 g.cm^3 and M=153.8 g/mol a) Demonstrate that close to 1 atm (dU/dP)t ~

Carbon tetrachloride CCl4 at 20o C has a=12.4x10^-4, b=103x10^-6 atm^-1 p=1.5942 g.cm^3 and M=153.8 g/mol


a) Demonstrate that close to 1 atm (dU/dP)t ~ -VTa

b) Under these conditions what is the value of dU

 

O tetracloreto de carbono, CCl, a 20 C possui a = 10-6 atm-1, p = 1,5942 g.cm3 e M = 153,8 g/mol. (a) Demonstre que prximo a 1 atm (aU /aP), -VTa. (b) Nessas condies, qual o valor de AU. 12,4 10-4 K-1, B = 103

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