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Choose as a basis function y ( 0 ) = f ( S , N 1 , N 2 , N 3 , P )

Choose as a basis function
y(0)=f(S,N1,N2,N3,P)
and obtain y12(1) in terms of derivatives of the basis function. Discuss how experi-
ments could be designed and conducted to obtain numerical values of the y(0)
derivatives.
Using your result, consider the following problem. We have a system con-
taining, initially, Ni moles of a material. We wish to remove Ni2mol under
conditions where the total entropy and the pressure remain constant. If the
initial temperature is 400K, what is the final temperature? Assume that the base
state for entropy is such that at 400K and the system pressure, the specific
entropy is 10JmolK. Also assume that the heat capacity is 10JmolK, inde-
pendent of temperature.
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