Consider a chronoamperometry experiment where the potential of a 0.10 cm2 planar electrode in a quiescent solution is stepped negative from 0.00 V versus Ag/AgCl while the current is measured. The analyte O has a concentration of 10 mM and the negative potential step causes its one-electron reduction to R (EO/R = -0.20 V versus Ag/AgCl). For the following parts, assume that both O and R have the same diffusion coefficient, DO = DR = 1.0 10-5 cm2s-1. (a) Use a spreadsheet to calculate and graph accurate concentration profiles of both for O and R near the electrode surface for a step potential of -0.50 V versus Ag/AgCl (i.e., well beyond EO/R) and at a time of t = 0.1 s. Then show on your graph how to estimate a Nernst diffusion layer thickness (). (b) The extreme potential step in part (a) results in a diffusion-limited current that is described by the Cottrell equation. Use a spreadsheet to calculate and graph that current for a time period of 1 s.