Question
Consider the following reaction between mercury(II) chloride and oxalate ion. 2 HgCl 2 ( aq ) + C 2 O 4 2- ( aq )
Consider the following reaction between mercury(II) chloride and oxalate ion.
2 HgCl2(aq) + C2O42-(aq) 2 Cl -(aq) + 2 CO2(g) + Hg2Cl2(s)
The initial rate of this reaction was determined for several concentrations of HgCl2 and C2O42-, and the following rate data were obtained for the rate of disappearance of C2O42-.
Experiment | [HgCl2] (M) | [C2O42-] (M) | Rate (M/s) |
---|---|---|---|
1 | 0.164 | 0.15 | 3.2 10-5 |
2 | 0.164 | 0.45 | 2.9 10-4 |
3 | 0.082 | 0.45 | 1.4 10-4 |
4 | 0.246 | 0.15 | 4.8 10-5 |
(a) What is the rate law for this reaction?
k[HgCl2]2[C2O4-2]k[HgCl2][C2O4-2]2 k[HgCl2]2[C2O4-2]1/2
(b) What is the value of the rate constant? M-2s-1 (c) What is the reaction rate when the concentration of HgCl2 is 0.16 M and that of C2O42- is 0.12 M if the temperature is the same as that used to obtain the data shown above? M/s
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