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Consider the mechanism for hydrogen and chlorine: Cl2 + M CI + CI + M, (R1) CI + H2 HCI + H, (R2) H+

Consider the mechanism for hydrogen and chlorine: Cl2 + M → Cl + Cl + M, CI + H2 → HCl + H, H+Cl2 → HCl + Cl, CI + Cl + M → Cl2 + M. (R1) (R02 (R3) (R4) (a) With appropriate steady-state assumptions, show that d[HCI] (b) If NCl3 is added to the mixture as an inhibitor, the following reaction needs to be considered: (R5) What is the rate expression in the limit of fast and slow rates of this reaction?  

Consider the mechanism for hydrogen and chlorine: Cl2 + M CI + CI + M, (R1) CI + H2 HCI + H, (R2) H+ Cl2 HCI + Cl, (R3) Cl+ Cl + M Cl2 + M. (R4) (a) With appropriate steady-state assumptions, show that d[HCI] = 2k ka [Cl2 [H2]. dt (b) If NCl3 is added to the mixture as an inhibitor, the following reaction needs to be considered: NCI3 + Cl NC2 + Cl2. (R5) What is the rate expression in the limit of fast and slow rates of this reaction?

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