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dev No: 4 Soru 1 ( 5 0 / 1 0 0 ) : n - oktanol ( 1 ) ve n - dekan (

dev No: 4
Soru 1(50/100): n-oktanol(1) ve n-dekan(2) Sv karmlarnn atmosfer basncndaki 300K scaklktaki karmadan kaynakl ortaya kan s deiimleri verisi llm ve aadaki eitlik elde edilmitir:
H=x1x2(A+B(x1-x2))Jmol
Burada A=2476;B=-1456.2
a) Bu ikili karm iin H1 ve H2 ksmi zelliklerini x1 mol fraksiyonuna karn 0-1 aralnda 0.1 adm artm esasl(0,0.1,0.2,dots,0.9,1.0) hesaplayp uygun bir bilgisayar program kullanarak (Python-Matplotlib modl veya MATLAB)x1'e gre grafiini iziniz (ayn grafikte iki ksmi zellik de yer almaldr).
b) Bu ikili karma ait ?bar(H)1 ve ?bar(H)2 ksmi zelliklerini x1 niceliinin bir fonksiyonu haline getirecek eitlikleri (ikisinin de y=ax13+bx12+cx1+d biiminde 3. derece polinom bir fonksiyona uymakta olduklar esasl) belirleyiniz. Eitliklerdeki a,b,c ve d katsaylarn, aadaki aralar zerinden hesaplatnz.
Excel kullanarak
Bir bilgisayar program kullanarak (Python-Numpy modlndeki polyfit) veya MATLAB)
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