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Diprotic acid dissociation reactions H 2 A H + + HA - , first proton dissociation constant, KA1 HA - H + + A 2-

Diprotic acid dissociation reactions

H2A H+ + HA-, first proton dissociation constant, KA1

HA-H+ + A2-, second proton dissociation constant, KA2

CT = [H2A] + [HA-] + [A2-]

Derive and express ionization factions (0, 1 and 2) as function of hydrogen ion concentration ([H+]).

Here, 0 = [H2A]/CT, 1 = [HA-]/CT, and 2 = [A2-]/CT

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