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III. The structure of 1 , 1 , 2 , 2 - tetraiododisilane is shown here. ( Reference: T . H . Johansen, K .

III. The structure of 1,1,2,2-tetraiododisilane is shown here. (Reference: T. H. Johansen, K. Hassler, G. Tekautz, K. Hagen, J. Mol. Struct .,2001,598,171.)
a. What is the point group of this molecule?
b. Predict the number of IR-active Si- I stretching vibrations.
Assign unit vectors on each atom and determine houthey transform based on the operations. The basis set is 1 if unchanged, 0 if they go somewhere else and -1 of the sign changes.
Once you generate the reducible representation, determine the rotational motions and translational motions so that the only remaining motions are vibrational.
c. Predict the number of Raman-active Si- I stretching vibrations.
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