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It is proposed to make a low alloy tungsten - nickel steel containing 1 % W and 1 % Ni while the carbon content should

It is proposed to make a low alloy tungsten-nickel steel containing 1%W and 1% Ni while
the carbon content should be 0.1%(all mass percentages). Using the following data you
are required to calculate the amount of NiO and WO3 the slag will contain (in mole fraction
Ni%+O%,=NiO(e),G16000=,+135620Jmol
W%+3Q%,=WO3(l),G1600o=,+55480Jmol
C(%)+O%,CO(g),logK=1168(T)+2.07
You can assume Pco=1.0 atm The slag is very basic (B>3.0) and its initial composition is
xcaO=0.6,xSiO2=0.19 and xFeO=0.21. Activity coefficients of NiO and WO3 in the sla
are 10-4 and 2.5610-6 respectively. Comment on the results. Assume Henry's law is
obeved by dilute components in steel.
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