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IV. (12) The complex: Mn(CO)sF, belong to Cav symmetry. It is required to obtain the expected Raman and IR spectra for Mn CO stretching bonds

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IV. (12) The complex: Mn(CO)sF, belong to Cav symmetry. It is required to obtain the expected Raman and IR spectra for Mn CO stretching bonds ( 5 Mn Co bonds) a) how many bands would be IR active? b) how many lines(p and dp) would be Raman active? c) how many bands would be both IR and Raman active? Hint: follow the movement of 5 bonds not atoms CO Z A, 1 Character table for Cay point group C. E 2C. (2) C20, 204 linear,rotations quadratic 1 1 R B1 -1 B21 -1 E 2 0 -2 0 0 (x, y) (Ry, Ry) (x2, yz) a = 1/h Eg x (I.R) (R)

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