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P 1 0 - 4 Consider the catalytic reaction as a function of the initial partial pressures 2 A B + C The rate of

P10-4 Consider the catalytic reaction as a function of the initial partial pressures
2AB+C
The rate of disappearance of species A was obtained in a differential reactor and is shown below.
(a) What species are on the surface?
(b) What does Figure B tell you about the reversibility and what's adsorbed on the surface?
(c) Derive the rate law and suggest a rate-liming step consistent with the above figures.
(d) How would you plot your data to linearize the initial rate data in Figure A?
(e) Assuming pure A is fed, and the adsorption constants for A and C are KA=0.5atm-1 and
KC=0.25atm-1 respectively, at what conversion are the number of sites with A adsorbed on the
surface and C adsorbed on the surface equal? (Ans.: x=0.66)
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