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Problem 1 ( modified Gaskell 9 . 2 ) ( 3 0 ' ) According to Gaskell's textbook Appendix A Table A . 4 ,

Problem 1(modified Gaskell 9.2)(30')
According to Gaskell's textbook Appendix A Table A.4, the standard vapor pressure of Mn:
lnp(atm)=-33440T-3.02lnT+37.68 at the temperature range xMn=0.5KMn1.50gMn1atmMnMnxMnFe-Mn1863K1517K.
When 1 mole of Argon gas is bubbled through a large volume ofanFe-Mn melt ofxMn=0.5at1863K evaporation ofMn into the Ar causes the mass of the melt to crease by1.50g. The mixing gas (ArMn) leaves the melt at a pressure of1atm. Please calculate:
(a). What is the partial pressure ofMnin the Ar-Mn mixing gas.
(b). What is the activity and activity coefficient ofMnin the liquid alloy.
(c). Please schematically draw the vapor pressure ofMnas a function ofxMnin the Fe-Mn melt at1863K.
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