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Q 1 3 . The catalytic isomerization of n - hexane to 2 - methylpentane and 3 - methylpentane was exhaustively discussed in Subsection 4

Q13. The catalytic isomerization of n-hexane to 2-methylpentane and 3-methylpentane was exhaustively discussed in Subsection 4.7.1. The effect of external mass transfer on selectivity was evaluated by assuming that the consecutive reactions were irreversible and first-order. In this problem, treat the realistic situation of reversible, first-order kinetics. Derive an expression for the selectivity of 2-methylpentane with respect to 3-methylpentane under isothermal conditions and for bulk-fluid concentrations of cAb,cBb and cRb. Express the result in terms of the two first-order, forward-direction rate constants, k1 and k2, the corresponding equilibrium constants, K1 and K2**, and the necessary mass-transfer coefficients between bulk fluid and catalyst surface.
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