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Q 1 4 . An aqueous solution of [ T i C l 6 ] 3 - showed an absorbance maxima at 1 3 0

14 .

An aqueous solution of

[T i C l_{6}]^{3 -}

showed an absorbance maxima at

13000 c m^{- 1}

with a broad hump at

12500 c m^{- 1}

in the UV

-

vis spectrum. Explain the origin of these transitions.

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