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Redlich-Kwong (RK) model is popularly used for equation of state and is described by V-b V+b) where R T RT a-0.42748 la, b-0.08664|--| , and
Redlich-Kwong (RK) model is popularly used for equation of state and is described by V-b V+b) where R T RT a-0.42748 la, b-0.08664|--| , and - For asymmetric molecules, the accuracy is improved by Redlich-Kwong-Soave (RKS) model which is the same as RK except that -II + m(1-T,0.5 r , where m1-0.480 + 1.5740-0. 1 760" and a) is the Pitzer acentric factor We want to quantify the error of RK in the molar volume V of methanol at T 300 C( 573.15 K) assuming that RKS represents reliable physical properties. Namely, the relative error is defined as RA The thermodynamic properties of methanol at the critical point are T512.6 K, P 79.9 atm, and -0. I 76 1 / mol . The Pitzer acentric factor of methanol is a)-0.559 Develop a function file HW6 YourLastName.m that calculates and plots the error & (y-axis) as a function of pressure P (x-axis). The function file should be executable as a stand-alone file. In the graph, the range of the pressure is 20 atm S PS 70 atm and the minimum of the axis should be 0. Label both axes in the graph. Explain why the error decreases as the pressure decreases. [Hint: Because T>T and PT and P
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