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Refer to the attached Txy diagram for vapor / liquid equilibrium for ethanol ( 1 ) / ethyl acetate ( 2 ) at 1 0
Refer to the attached Txy diagram for vaporliquid equilibrium for ethanolethyl acetate at kPa. Respond to the following questions with a few short sentences and some simple calculations. Feel free to copy the graph and draw on it to prove your answer.
a A mixture of ethanol and ethyl acetate is heated in a closed system at kPa to a temperature of and two phases are observed to be present. What are the possible compositions of the liquid and vapor phases?
b Consider a mixture with initially at and kPa. Describe the evolution of phases and phase compositions as the temperature is gradually increased to
c Consider a mixture with initially at and kPa. Describe the evolution of phases and phase compositions as the temperature is gradually reduced to
d Consider a closed vessel initially containing mol of pure ethyl acetate at and kPa. Imagine that pure ethanol is slowly added at constant temperature and pressure until the vessel contains mol ethyl acetate and mol ethanol. Describe the evolution of phases and phase compositions during this process. Comment on the practical feasibility of carrying out such a process. What sort of device would be required?
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