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Vinyl chloride is used to make polyvinyl chloride, or PVC , a widely used plastic with many applications. As part of the process to produce

Vinyl chloride is used to make polyvinyl chloride, or PVC, a widely used plastic with many
applications. As part of the process to produce vinyl chloride, ethylene is reacted with
chlorine gas to produce 1,2-dichloroethane. 1,2-dichloroethane is then heated to produce
vinyl chloride. You are tasked with designing a flash drum to remove unreacted ethylene
from 1,2-dichloroethane before the heating step so the ethylene can be recycled to the
reactor. 90mols of a mixture of 86mol%1,2-dichloroethane (DCE) and 14mol% ethylene
(E) at 298.15K is to be flashed from 5 bar to 2 bar. The desired liquid composition is 97
mol%1,2-dichloroethane. Assume Raoult's Law applies (an ideal mixture). Antione's
Equation (log10) parameters are given below for P(?bar) and T(K).
a. Draw a process flow diagram and do a degree of freedom analysis.
b. Calculate the temperature (K) of the flash drum and the molar flow rates
(mols) and compositions of the product streams analytically.
(30 pts) Vinyl chloride is used to make polyvinyl chloride, or PVC, a widely used plastic with many applications. As part of the process to produce vinyl chloride, ethylene is reacted with chlorine gas to produce 1,2-dichloroethane. 1,2-dichloroethane is then heated to produce vinyl chloride. You are tasked with designing a flash drum to remove unreacted ethylene from 1,2-dichloroethane before the heating step so the ethylene can be recycled to the reactor. 90mols of a mixture of 86mol%1,2-dichloroethane (DCE) and 14mol% ethylene (E) at 298.15K is to be flashed from 5 bar to 2 bar. The desired liquid composition is 97mol%1,2-dichloroethane. Assume Raoult's Law applies (an ideal mixture). Antione's Equation (log10) parameters are given below for P(?bar) and T(K).
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