Question
W. Deng and K. W. Hipps (J. Phys. Chem. B 2003, 107, 10736-10740) reported an STM study of the electronic properties of Ni(ll)tetraphenyl porphyrin (NiTPP),
W. Deng and K. W. Hipps (J. Phys. Chem. B 2003, 107, 10736-10740) reported an STM study of the electronic properties of Ni(ll)tetraphenyl porphyrin (NiTPP), a red-purple, neutral diamagnetic complex that is made by reacting Ni(II) perchlorate with tetraphenylporphine.
When NiTPP is reacted with sodium thiocyanate it forms another complex that is paramagnetic. Draw the structures of NiTPP and the product complex, and the crystal field energy level diagram that explains each. What value of the magnetic moment (in units of MB) would you expect for the paramagnetic complex?
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The structures of NITPP and the product complex NiNa2TPPSCN2 can be drawn as foll...
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Fundamentals of biochemistry Life at the Molecular Level
Authors: Donald Voet, Judith G. Voet, Charlotte W. Pratt
4th edition
470547847, 978-0470547847
