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You propose two reaction mechanisms for a reaction you are studying. You experimentally determine that the overall reaction is lst order with respect to (

You propose two reaction mechanisms for a reaction you are studying. You
experimentally determine that the overall reaction is lst order with respect to
(CH3)3CBr and 0 th order with respect to cyanide. Which mechanism(s) is/are valid?
Explain your answer.
Mechanism A
Step 1: (CH3)3CBr(CH3)3C++Br-
Step 2: (CH3)3C++CN-(CH3)3CCN
Overall: (CH3)3CBr+CN-(CH3)3CCN+Br-
Mechanism B
Single-step: (CH3)3CBr+CN-(CH3)3CCN+Br-
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