Consider the PtS net listed in Table 1.6. The dehydrated form of MOF-11 has composition Cu₂(ATC) where ATC is 1,3,5,7-adamantane tetracarboxylate and contains a Cu paddle-wheel unit analogous to the Zn dimer shown in Figure 14.13. Describe the structure of PtS. Based on the information given and your chemical knowledge, suggest possible structures for MOF-11 and ZnPt(CN)₄.

Table 1.6

Figure 14.13

N.M 4,2 4,3 4,3 4,4 4.4 4,4 6,2 6,3 6,4 6,6 6,6 8,4 8,8 Cation coordination Tetrahedron Tetrahedron Square Tetrahedron Square Square Octahedron Octahedron Octahedron Octahedron Octahedron Cube Cube Anion coordination Linear (bent) Triangle Triangle Tetrahedron Tetrahedron Square Linear Triangle Tetrahedron Octahedron Trigonal prism Tetrahedron Cube Example SiO (in quartz, cristobalite, tridymite) Si3N4 Pt304 ZnS (in zinc blende, wurtzite) PtS Nbo ReO3 TiO (in rutile, anatase, brookite) AlO3 (in corundum) NaCl NiAs CaF CSCI