Haag and co-workers measured the cracking rate of n-hexane by HZSM-5 relative to a high-surface-area catalyst under

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Haag and co-workers measured the cracking rate of n-hexane by HZSM-5 relative to a high-surface-area catalyst under identical experimental conditions. The dependence of the rate on the Al:Si ratio and on the intensity of the signal due to tetrahedral Alsitesin the 27Alsolid state NMR are shown in the figures below. State what you can conclude from the linear dependence of activity on both the Al:Si ratio and the NMR signal from tetrahedral sites.

1000 relative cracking activity 100 10 0.1 0.00001 0.001 Al:Si ratio 0.1 relative cracking activity 250 200

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Solid State Materials Chemistry

ISBN: 9780521873253

1st Edition

Authors: Patrick M. Woodward, Pavel Karen, John S. O. Evans, Thomas Vogt

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