A mixture of Si(OCH 3 ) 4 , (CH 3 ) 4 NOH(aq), and Al(OCH 2 CH
Question:
A mixture of Si(OCH3)4, (CH3)4NOH(aq), and Al(OCH2CH2CH3)3 was heated to drive off alcohol, resulting in a clear solution. This solution was heated at 130 °C in a sealed autoclave for 8 days. The resulting white precipitate was washed with distilled water and dried at 100 °C, yielding a white powder A whose X-ray-diffraction pattern was very similar to that of the mineral gismondine (CaAl2Si2O8·4H2O). Chemical analysis of A gave weight percentages N 4.2%, C 14.5%, H 4.2%, Al 8.1%, Si 25.4%, O 43.5%.
(a) Calculate the empirical formula of A.
(b) Given that the X-ray-diffraction pattern is similar to gismondine, suggest a sensible molecular formula for A.
(c) In light of your answer to (a) and (b), discuss how template molecules may be used to influence the hydrophilicity of zeolites.
Step by Step Answer:
Solid State Materials Chemistry
ISBN: 9780521873253
1st Edition
Authors: Patrick M. Woodward, Pavel Karen, John S. O. Evans, Thomas Vogt