The vapor pressure of toluene is given in Exercise 4.8, and that of n-heptane is given in
Question:
The vapor pressure of toluene is given in Exercise 4.8, and that of n-heptane is given in the accompanying table.
(a) Plot an x-y equilibrium diagram for this system at 1 atm by using Raoult's and Dalton's laws.
(b) Plot the T-x bubble-point curve at 1 atm.
(c) Plot a and K-values versus temperature.
(d) Repeat part (a) using the arithmetic average value of a, calculated from the two extreme values.
(e) Compare your x-y and T-x-y diagrams with the following experimental data of Steinhauser and White.
Transcribed Image Text:
VAPOR PRESSURE OF n-HEPTANE Vapor pressure, torr: 60 100 200 400 760 1,520 20 40 Temperature, "C: 58.7 41.8 78 0 98.4 9.5 22.3 30.6 124 VAPOR-LIQUID EQUILIBRIUM DATA FOR n-HEPTANE/TOLUENE AT I ATM T,°C Xn-heptane Fn-heptane 0.048 0.025 110.75 0.129 0.205 106.80 0.250 0.349 104.50 0.354 0.454 102.95 0.497 0.577 101.35 0.692 0.742 99.73 0 864 0.843 98.90 0.940 0.948 98.50 0.994 0.993 98.35
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