Question: You are given vapor pressure data in the form of [T (C). p (mm Hg)] pairs. Construct a spreadsheet or write a computer program to
You are given vapor pressure data in the form of [T (°C). p (mm Hg)] pairs. Construct a spreadsheet or write a computer program to perform the following tasks:
(a) Read in Tt, p1, T2, p2,..., TN, pN.
(b) Fit the Clausius—Clapeyron equation to the data using the method of least squares (Appendix A.1) or a fitting routine embedded in the spreadsheet. In completing this task you should find the values of a and b in the formula y = ax + b, where y = In p* and x = 1/(T + 273.2). Print out the values of a and b.
Test your program by fitting the data for ethylene glycol given in Problem 6.4. Then use your formula to estimate the vapor pressures of this substance at 50°C, 80°C, and 110°C, and the boiling points at 760 mm Hg and 2000 mm Hg. In which of the last two values would you have the least confidence? Explain your reasoning.
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TC pmm Hg 797 5 20 40 100 0002410 400 0002214 760 0002125 1058 1200 In ... View full answer
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