Chlorine can be absorbed from C1 2 -air mixtures by olefins dissolved in CCl 4 . It
Question:
Chlorine can be absorbed from C12-air mixtures by olefins dissolved in CCl4. It was found that the reaction of C12, with cyclo-hexene (C6H10) is second order with respect to Cl2 and zero order with respect to C5H10. Hence the rate of disappearance of C12 per unit volume is k2 CA (where A designates C12. Treat this as a binary solution of A (C12 and B (C6H10- CCl4 mixture), pseudobinay assumption. Assume that air is insoluble in the C6H33- CCl6 mixture. Let the liquid phase to be sufficiently deep with L can be taken to be infinite. Find the correlation describing the concentration profile and obtain expression for the rate of absorption of by the liquid.
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Fundamentals Of Momentum Heat And Mass Transfer
ISBN: 9781119723547
7th Edition
Authors: James Welty, Gregory L. Rorrer, David G. Foster