The rate law of the reaction 2 NO(g) + 2 H 2 (g) N 2 (g)

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The rate law of the reaction 2 NO(g) + 2 H2(g) → N2(g) + 2 H2O(g) is Rate = kr[NO]2[H2], and the mechanism that has been proposed isStep 1 NO + NO NO Step 2 NO + HNO + HO Step 3 NO + HN + HO

(a) Which step in the mechanism is likely to be rate determining? Explain your answer. 

(b) Sketch a reaction profile for the overall reaction, which is known to be exothermic. Label the activation energies of each step and the overall reaction enthalpy.

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Chemical Principles The Quest For Insight

ISBN: 9781464183959

7th Edition

Authors: Peter Atkins, Loretta Jones, Leroy Laverman

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