Oxygen atoms can combine with ozone to form oxygen: Using r H and the bond dissociation

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Oxygen atoms can combine with ozone to form oxygen:Os(g) + O(g)  2 O2(g)  = -392 kJ/mol-rxn

Using ΔrH° and the bond dissociation enthalpy data in Table 8.8, estimate the bond dissociation enthalpy for the oxygen–oxygen bond in ozone, O3. How does your estimate compare with the energies of an O—O single bond and an O=O double bond? Does the oxygen–oxygen bond dissociation enthalpy in ozone correlate with its bond order?

Data given in table 8.8

TABLE 8.8 Some Average Bond Dissociation Enthalpies (kJ/mol)* Single Bonds F Si 328 H C N 0 F Si P S CI Br B

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Chemistry And Chemical Reactivity

ISBN: 9780357001172

10th Edition

Authors: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

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