Gold is isolated from rocks by reaction with aqueous cyanide, CN - : 4 Au(s) + 8

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Gold is isolated from rocks by reaction with aqueous cyanide, CN-: 4 Au(s) + 8 NaCN(aq) + O2(g) + H2O(l) → 4 Na[Au(CN)2](aq) + 4 NaOH(aq). 

(a) Which atoms from which compounds are being oxidized, and which atoms from which compounds are being reduced? 

(b) The [Au(CN)2]- ion can be converted back to Au(0) by reaction with Zn(s) powder. Write a balanced chemical equation for this reaction. 

(c) How many liters of a 0.200 M sodium cyanide solution would be needed to react with 40.0 kg of rocks that contain 2.00% by mass of gold?

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Chemistry The Central Science

ISBN: 978-0134414232

14th Edition

Authors: Theodore Brown, H. LeMay, Bruce Bursten, Catherine Murphy, Patrick Woodward, Matthew Stoltzfus

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