(a) What cluster valence electron (CVE) count is characteristic of octahedral and trigonal prismatic complexes? (b) Can...
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(a) What cluster valence electron (CVE) count is characteristic of octahedral and trigonal prismatic complexes?
(b) Can these CVE values be derived from the 18-electron rule?
(c) Determine the probable geometry (octahedral or trigonal prismatic) of [Fe6(C)(CO)16]2− and [Co6(C)(CO)16]2−. (The C atom in both cases resides in the centre of the cluster and can be considered to be a four-electron donor.)
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ANSWER a Cluster Valence Electron CVE Count for Octahedral and Trigonal Prismatic Complexes For octahedral complexes the characteristic Cluster Valenc...View the full answer
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Related Book For 
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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