Using data from Appendix 11, and the value for the standard Gibbs energy of formation for PbS
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Using data from Appendix 11, and the value for the standard Gibbs energy of formation for PbS of −99 kJ mol–1, determine a value for Ksp for this salt.
Data from Appendix 11
The concentration of each aqueous solution is 1 mol dm−3 and the pressure of a gaseous component is 1 bar (105 Pa). (Changing the standard pressure to 1 atm (101 300 Pa) makes no difference to the values of E° at this level of accuracy.) Each half-cell listed contains the specified solution species at a concentration of 1 mol dm−3; where the half-cell contains [OH]−, the value of E° refers to [OH−] = 1 mol dm−3, hence the notation E°[OH−] = 1
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