(a) For each of the two reactions shown in Fig. P17.58, suggest a mechanism that is consistent...

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(a) For each of the two reactions shown in Fig. P17.58, suggest a mechanism that is consistent with all of the experimental facts given.


Experimental observations:

(1) Both reactions conform to the following rate law, although the rate constants for each reaction are different.rate = k[alkyl halide][Et NH]

(2) The alkyl chloride starting materials do not interconvert under the reaction conditions.

(3) The following compound, prepared separately, is not converted into the observed product under the reaction conditions.CH3 T HC=CH-CHNHt CH- +

In particular, explain the importance of facts (2) and (3) in understanding the mechanism.


(b) The mechanism of reaction 2 is called the SN2′ mechanism. Suggest a reason why this reaction occurs by the SN2′ mechanism and reaction 1 does not.Reaction 1: HC-CH=CH-CH-Cl + EtNH (trans) Reaction 2: HC-CH-CH=CH + EtNH - 1 CI Figure P17.58

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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