Primary alcohols, when treated with H 2 SO 4 , do not dehydrate to alkenes under the

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Primary alcohols, when treated with H2SO4, do not dehydrate to alkenes under the usual conditions. However, they do undergo another type of “dehydration” to form ethers if heated strongly in the presence of H2SO4. The reaction of ethyl alcohol to give diethyl ether is typical:2 EtOH ethanol HSO4 140 C Et-O-Et + HO diethyl ether

Using the curved-arrow notation, show mechanistically how this reaction takes place.

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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