Harnet and Hamer [J. American Chemical Society 57 (1935): 33] report values for the potential of the
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Harnet and Hamer [J. American Chemical Society 57 (1935): 33] report values for the potential of the cell Pt(s) PbSO4(s) H2SO4(aq, a) PbSO4(s) PbO2(s) Pt(s) over a wide range of temperature and H2SO4 concentrations. In 1m H2SO4, their results were described by E(V) = 1.91737 + 56.1 × 10−6 t + 108 × 10−8 t2,where t is the temperature on the Celsius scale. Calculate ΔGR, ΔHR, and ΔSR for the cell reaction at 11° and 35°C.
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