Use the relation the cyclic rule and the van der Waals equation of state, to derive an

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Use the relation

aV Әт. ӘР Cr m = T Сри — Сти — Әт Әт

the cyclic rule and the van der Waals equation of state, to derive an equation for CP,m ˆ’ CV,m in terms of Vm, T, and the gas constants R, a, and b.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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