The three chromatograms shown here were obtained with 2.5, 1.0, and 0.4 mL of ethyl acetate injected

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The three chromatograms shown here were obtained with 2.5, 1.0, and 0.4 mL of ethyl acetate injected on the same column under the same conditions. Explain why the peak becomes less symmetrical with increasing sample size.

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