Question
1. In an electroless deposition of Cu+ using Fe in acidic medium, the mechanism is shown below: Cu+ +2e=Cu (Ed=0.34 V SHE) and Fe=Fe+
1. In an electroless deposition of Cu+ using Fe in acidic medium, the mechanism is shown below: Cu+ +2e=Cu (Ed=0.34 V SHE) and Fe=Fe+ + 2e- (E= -0.41 V SHE). identify the oxidation and reduction reactions (i) (ii) (iii) Can H gas be used instead of Fe? Why? Can O gas used instead of Fe (E = 1.23 V SHE)? Why? (iv) Identify the direction of electrons flow and current flow. B. Can we get work from the above cell? If yes, how? If no, why? [6 points] [4 points].
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SOLUTION A i Oxidation reaction Cu2 2e Cu Reduction reaction Fe2 2e Fe ii Yes H2 gas can be used instead of Fe The reduction of Cu2 to Cu can be done by hydrogen gas and the reaction is Cu2 2H2 Cu 2H ...Get Instant Access to Expert-Tailored Solutions
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General Chemistry Principles And Modern Applications
Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette
11th Edition
0132931281, 978-0132931281
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