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(d) In a Hittorf cell with silver electrode contains a 0.01 molal Ag NO3 solution and a silver coulometer is connected in series. Electrolysis

 

(d) In a Hittorf cell with silver electrode contains a 0.01 molal Ag NO3 solution and a silver coulometer is connected in series. Electrolysis is continued for some time. Analysis after electrolysis, shows. (i) 32.10 mg of Ag is deposited in the coulometer. (ii) 20.09 gm of solution of the anode chamber of the Hittorf cell contains 39.66 mg of +6 Ag +6 . Calculate the transport number of cation ( t ) {Ag = 107.9 N=14, 0 = 16. [3 marks]

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