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4. Previous CHE 430 exam problem. The isomerization of 1-butanol (A) to isobutanol (B) is conducted over acid resin catalyst in the gas phase under

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4. Previous CHE 430 exam problem. The isomerization of 1-butanol (A) to isobutanol (B) is conducted over acid resin catalyst in the gas phase under conditions where both butanol isomers can be treated as ideal gases. CH3 OH H3C OH H3C B From a paper published in Chemical Engineering Science, the following data on the equilibrium of the 1-butanol isomerization reaction has been reported. At 150C, the equilibrium pressure of A is 0.23 atm and B is 0.77 atm. Additionally, the same paper examined the kinetics of isomerization and found the over a wide range of conditions, the net rate for the disappearance of 1-butanol (A) had the following form - ra = k Cd-k,Cg where kf= 7.7 L/gcat-min at 150C Pure reactant A is fed into the reactor with a molar flow rate of 134 mol/min at a total pressure of 1.0 atm. a. What is the amount (in g) of acid resin catalyst necessary to produce a stream exiting a packed bed reactor (PBR) with an isobutanol (B) partial pressure of 0.15 atm. The reactor temperature is set to 150C. b. The AGrxn for 1-butanol isomerization can be considered independent of temperature. A vant Hoff analysis of the 1-butanol isomerization reaction has shown that the reaction is exothermic (AH

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