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( a ) A small amount of SiO 2 powder ( 5 wt % ) is added to a fine YAG powder, in hopes of

(a) A small amount of SiO2 powder (5 wt%) is added to a fine YAG powder, in hopes of densifying the powder compact into a transparent polycrystaline YAG (suitable for IR window material) by forming a minor amount of liquid phase during firing. After mixing uniformly, the powder mixture is pressed into a pellet and rapidly heated in a furnace. What is the minimum temperature (approximately) at which a liquid phase might form? What is the corresponding liquid composition?
(b) After firing the pellet at 1800\deg C for many hours, the sample is cooled to room temperature at a rate slow enough to maintain equilibrium. Upon reheating, at what temperature would a liquid first form in this sample? What would be the liquid composition? (Explain how you arrived at your answer.)
(c) In a separate study, fine Y2O3 and SiO2 powder are added to Al2O3 powder as liquid-phase sintering aids. The overall composition is 80 wt % Al2O3,15% SiO2 and 5% Y2O3. If the sample is equilibrated at 1700\deg C, what phases are present, and in what amounts?
(d) Toward the SiO2-rich end of the SiO-Y2O3 join, there exists a region of liquid immiscibility where two liquid phases are present at equilibrium. Can you determine from this phase diagram the exact compositions of the two liquids? The approximate composition? Explain.
(e) What is the most refractory (highest melting) three-phase composite one can prepare in this ternary system?
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