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Experimental data for the gas-phase catalytic reaction A+BC is shown below. The limiting step in the reaction is known to be irreversible, so that the
Experimental data for the gas-phase catalytic reaction A+BC is shown below. The limiting step in the reaction is known to be irreversible, so that the overall reac- tion is irreversible. The reaction was carried out in a differential reactor to which A, B, and C were all fed. Run Number PA (atm) PB (atm) Pc (atm) Reaction rate (mol)/(g-cat s) 0 1 2 3 4 5 6 7 1 1 10 1 1 20 0.1 1 10 1 20 20 1 N 4 4 4 4 0.114 1.140 0.180 2.273 0.926 0.186 0.0243 10 2 (a) Suggest a rate law consistent with the experimental data. Hint: Sketch (- ) as a function of P, as a function of Pb, and as a function of Pc. (b) From your rate expression, which species can you conclude are adsorbed on the surface? (c) Suggest a rate law and then show that your mechanism is constant with the rate law in part (a)
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