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Helmholtz free energy is a generating function Problem 1 7 If the Helmholtz free energy is given by: A ( T , V ) =

Helmholtz free energy is a generating function

Problem

17

If the Helmholtz free energy is given by:

A (T, V) = - R T l n (V - b) - \frac{a}{V} + c (T)

Derive:

Pressure

Entropy

Internal energy

isothermal compressibility

volume expansivity

Heat capacity at constant volume

The second virial coefficient

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