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Q ) An approximate expression for the total driving force for precipitation in a regular solution is G 0 = R T [ x 0

Q) An approximate expression for the total driving force for precipitation in a regular solution
is
G0=RT[x0In(x0xe)+(1-x0)In((1-x0)(1-xe))]-(x0-xe)2
(a) Use this equation to estimate the total free energy
released when '+ at 600K if x0=0.1,xe=0.02
and =0(ideal solution)(R=8.31Jmol-1KT-1).
(b) Estimate the volume fraction of precipitate at equilibrium if is pure solute (xB=1).
(Assume the molar volume is constant.)
(c) If the alloy is heat treated to produce a precipitate dispersion with a spacing of 50nm
estimate the total interfacial area, m-3 of alloy. (Assume a simple cubic array.)
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