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SORU 2 ( 6 0 1 0 0 ) a ) Mol olarak % 4 0 N 2 ve % 6 0 C H 4

SORU 2(60100)
a) Mol olarak %40N2 ve %60CH4 ieren bir gaz karm,200K ve 30 bar koullarnda bulunmaktadr. Gaz karmnn entalpi (H) ve entropi (S) deerlerini, sz konusu karmn Redlich-Kwong hal denklemi ile modellenebilmekte olmas ve aadaki veriler esasl belirleyiniz:
300K ve 1 bar koullarnda ideal davranm gsteren bu gaz karmnn H ve S deerleri, srasyla 12286J*mol-1 ve 146.75J*mol-1*K-1 olarak verilmektedir. Sz konusu bu deerler, Blm 9'daki Gibbs teoremi ve
www.nist.gov.tr sitesindeki saf madde zellikleri zerinden belirlenmitir.
CPigR=A+BT+CT2
b) Saf haldeki N2 ve CH4 gazlarnn 200K ve 30 bar koullarndaki Z,HR ve SR deerlerini, Redlich-Kwong hal denklemi esasl belirleyiniz. Saf maddelerin Redlich-Kwong hal denklemi esasl, belirli bir T ve P koullarndaki Z,HR ve SR deerlerini hesaplayan bir bilgisayar program yaznz. Aadaki tabloyu, programnzaltrmak suretiyle doldurunuz:
\table[[,T=200K;P=30bar,,T=300K;P=1bar
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