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The figure below shows a TEM micrograph of a rubber toughened polystyrene, PS , in which the rubber particles are indicated by arrows. The rubber,

The figure below shows a TEM micrograph of a rubber toughened polystyrene, PS, in which the rubber particles are indicated by arrows. The rubber, which has a Tg of -60oC, can decrease the Tg of the PS (which has a Tg of 100oC), however.
a) The fracture toughness of the HIPS sample is 15 kJ/m2 vs.0.4 for pure PS. A typical method for measuring this property involves placing a small crack in the sample, applying a stress and measuring its resistance to brittle fracture, as seen in the figure below. Discuss the mechanism(s) by which the rubber increases the fracture toughness of HIPS relative to pure PS.
b) How much rubber must be added in order to decrease the Tg of PS
to 65oC?
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